awk '{sub(/[^A-Z]*/,"")}
     /^VIRTUAL/{j=k=l=i;V[i++]=$2}
     /^SERVICE/{S[j++]=$2} j>i{i++}
     /^POOL/   {P[k++]=$2} k>i{i++}
     /^MEMBER/ {M[l++]=$2} l>i{i++}
     END       {print "VIRTUAL         SERVICE  POOL                  MEMBER" ;
                for (j=0;j<i;j++) printf "%-15s %-8s %-21s %s\n",V[j],S[j],P[j],M[j]}' 'RAW Input.txt'

VIRTUAL         SERVICE  POOL                  MEMBER
ANY                      Default_router        10.65.8.253:*
192.168.1.1
192.168.1.2
192.168.1.3
192.168.1.4
192.168.1.5
192.168.1.5
192.168.1.6
192.168.1.7
192.168.1.8     80       TermWiki-stag         192.168.1.2:80
                                               192.168.1.2:80
192.168.1.9     80       IIS-UAT-WebFarm-V4    192.168.1.2:80
                                               192.168.1.2:80
192.168.1.10    80       Distribution-pac-uat  192.168.1.2:80
                                               192.168.1.2:80

For every line in the input file:
1. Delete any character before the first capital letter
2. line starts with VIRTUAL: synchronize counters; put field 2 in array V; increment line counter i
3. line starts with SERVICE: put field 2 in array S; increment line counter j, if it is more than i then increment i
4. line starts with POOL:    put field 2 in array P; increment line counter k, if it is more than i then increment i
5. line starts with MEMBER:  put field 2 in array M; increment line counter l, if it is more than i then increment i

After the last line is read:
6. Print Header
7. for j=0 until i-1 use j as the index for V S P and M and print the content using printf formatting.