A Facile Synthesis of Functionalized Bis(arylethynyl)benzene Derivatives via Sila-Sonogashira Reacti

 
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Old 11-09-2010
A Facile Synthesis of Functionalized Bis(arylethynyl)benzene Derivatives via Sila-Sonogashira Reacti

HPL-2010-185 A Facile Synthesis of Functionalized Bis(arylethynyl)benzene Derivatives via Sila-Sonogashira Reaction - Zhou, Zhang-Lin; Zhao, Lihua; Zhang, Sean; Vincent, Kent; Lam, Sity; Henze, Dick
Keyword(s): Bis(arylethynyl)benzene derivatives, Cross-coupling reaction, Sila-Sonogashira reaction.
Abstract: This paper describes a facile synthesis of a new series of symmetrical bis(arylethynyl)benzene derivatives via a one-pot coupling reaction between trialkylsilyl protected arylalkynyes and aryldihalides bearing both electron-withdrawing (EW) and electron-donating groups (ED) in the presence of PdCl2( ...
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VASY(1) 						     CAO-VLSI Reference Manual							   VASY(1)

NAME
VASY - VHDL Analyzer for Synthesis ORIGIN
This software belongs to the ALLIANCE CAD SYSTEM developed by the ASIM team at LIP6 laboratory of Universite Pierre et Marie CURIE, in Paris, France. Web : http://asim.lip6.fr/recherche/alliance/ E-mail : alliance-users@asim.lip6.fr SYNOPSIS
vasy [-VpavsoipSHL] [-C num] [-E num] [-I format] [-P file] filename [outname] DESCRIPTION
VASY is a hierarchical VHDL Analyzer for Synthesis. VASY performs a semantic analysis of a VHDL RTL description filename, with a VHDL sub- set much more extended than the Alliance one (see vasy(5) for more details), and identifies with precision all the memorizing elements and tristate buffers. During its analysis, VASY expands generic parameters, executes generic map and generate statements, and also unrolls static FOR loops. At the end, VASY drives an equivalent description outname (in Verilog or VHDL format) accepted by most of synthesis tools. ENVIRONMENT VARIABLES
MBK_WORK_LIB(1) indicates the path to the read/write directory for the session. OPTIONS
-V Verbose mode on. Each step of the analysis is displayed on the standard output. -v Drives an equivalent description in Verilog format. -a Drives an equivalent description in Alliance VHDL format vbe(5) and/or vst(5). We can note that with this option, all arithmetic operators are expanded in an equivalent set of boolean expressions, because these operators don't belong to the Alliance VHDL subset. -s Drives an equivalent VHDL description (with the extention .vhd) accepted by most of industrial synthesis tools. -S Uses Std_logic instead of Bit (taken into account only with option -s). -i Drives initial signal values (taken into account only with option -s). -I format Specifies the VHDL input format such as Alliance VHDL format vbe(5), vst(5) or industrial VHDL format vhd or vhdl. -H In a structural description, all model of instances are recursively analyzed. (By default VASY analyzes only models with generic parameters) The leaves cells are defined by a file called CATAL (see catal(5) for details). -o Authorizes to overwrite existing files. -p Adds power supply connectors (vdd and vss). Usefull option to enter in Alliance. -C num When the size of the adder is greater or equal to num a Carry Look Ahead adder is generated, instead of a Ripple Carry adder. (taken into account only with option -a). -E num Comparators are expanded in an equivalent set of boolean expressions, when their size is greater than num (taken into account only with option -a). -L A file .lax (see lax(5) for details) is generated. This file contains the list of all signals that must be kept during the syn- thesis step, using boom (see boom(1) for details). (taken into account only with option -a). -P file Specifies a 'file.pkg' containing a list of logical and physical package name: # Example work.constants.all : pkg_constants work.components.all : pkg_components SEE ALSO
vasy(5), vbe(5), vhdl(5), catal(5). lax(5). asimut(1), boom(1), MBK_WORK_LIB(1). MBK_CATA_LIB(1). MBK_CATAL_NAME(1). BUG REPORT
This tool is under development at the ASIM department of the LIP6 laboratory. We need your feedback to improve documentation and tools. ASIM
/LIP6 November 26, 1999 VASY(1)