export CLASSPATH=/your/stuff/
or preserving system wide settings:
export CLASSPATH=$CLASSPATH:/your/addition/
the only different from Windows in terms of path-separators, : instead of ;
For example
java -classpath /mydir/mylib.jar:/otherdir/otherlib.jar com.MyProgram -Xmx64m
wildcard in the classpath to add multiple jars
java -cp "Halo.jar:lib/*" ni.package.MainClass
Java Path and Java ClassPath
Anto